Further to IAUC 8203 Mario Hamuy and Miguel Roth, Carnegie Observatories, report that a spectrum (range 380-930 nm) of SN 2003id (cf. IAUC 8201), obtained on Oct. 16.27 with the Las Campanas Dupont 2.5-m telescope + WFCCD) reveals unusual features. While the spectrum is characterized by strong absorptions between 466-536 nm (presumably due to Fe II blends) seen in other Type Ic events, a strong unidentified absorption centered at 562 nm distinguishes it from other Type Ic or Type Ib supernovae. This feature is blended with another strong absorption centered at 579 nm. The spectrum shows a strong Ca II triplet line exhibiting a broad P-Cyg profile with the minimum at 826 nm. Adopting the NED host-galaxy recession velocity of 2288 km/s, the minimum of the Ca II triplet implies an expansion velocity of -13000 km/s which is very high for a supernova that is at least one month old. The optical lightcurves are also unusual: the V-band flux decreased by ~0.25 mag between Sept. 19 and 25; a plateau phase (V=17.25) ensued through Oct. 3; the flux has been dropping afterwards reaching V=18.6 on Oct 16. Further observations at optical and other wavelengths would be useful.